Tetra-μ-acetato-κ8 O:O′-bis{[N-(4-methylphenyl)pyridin-2-amine-κN 1]copper(II)}(Cu—Cu)
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چکیده
The complete dinuclear mol-ecule of the title complex, [Cu(2)(CH(3)COO)(4)(C(12)H(12)N(2))(2)], is generated by a centre of inversion. The Cu(II) atoms are connected [Cu-Cu = 2.6329 (16) Å] and bridged by four acetate ligands. The distorted octa-hedral coordination geometry is completed by a terminal pyridine N atom. The amine H atom forms an intra-molecular N-H⋯O hydrogen bond.
منابع مشابه
Tetra-μ-acetato-κ8 O:O′-bis{[2-methylsulfanyl-4-(pyridin-4-yl-κN)pyrimidine]copper(II)}(Cu—Cu)
The binuclear title compound, [Cu(2)(CH(3)CO(2))(4)(C(10)H(9)N(3)S)(2)], comprises a Cu(2)(CH(3)CO(2))(4) paddle-wheel core axially bound by two 2-methyl-sulfanyl-4-(pyridin-4-yl)pyrimidine ligands. The complex mol-ecule has an inversion center lying at the mid-point of the Cu-Cu bond.
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